Провідні катіон-радикальні солі фульваленів із складними метало-аніонами

Abstract

Chudak D.M. Conductive radical-cation salts of fulvalenes with complex meta- anions. Qualification scholarly paper: a manuscript. The Thesis submitted for obtaining the Doctor of Philosophy degree in Natural Sciences, Speciality 102 – Chemistry. V. N. Karazin Kharkiv National University, Ministry of Education and Science of Ukraine, Kharkiv, 2021 Actuality of theme. One of the fundamental tasks of science and technology is the creation of new materials with combined properties. Among such materials, traditionally, one of the important places is occupied by molecular conductors, which are increasingly being widely used. The ability to have the properties of metals is common among inorganic compounds, and in organic compounds the metallic state is an exceptional phenomenon. For example, in graphite in the plane of the aromatic rings, there is a metallic conductivity. Also, electrical conductivity is observed in some inorganic compounds of the type charge-transfer complexes and organic conjugated systems such as the doped trans-polyacetylene.